Aspen Adsorption Tutorial Pdf
Corporate Aspen Technology, pharmacology illustrated review pdf Inc. This document is intended as a guide to using AspenTech's software.
Mass transfer resistance between the bulk gas phase and the gas-solid interface. You choose these isotherms from the Configurure Layer forms for the layers making up the bed model. This submodel needs the relationship between the component rates of mass transfer and the local bed conditions. Fluid The mass transfer driving force is expressed as a function of the liquid phase concentration liquid film. Lumped Resistance Here, the separate resistances to mass transfer is lumped as a single overall factor, or one mass transfer resistance dominates the others.
User Submodel With User Submodel selected, you supply the isotherm relationship through the user submodel iUserIsotherm. The values of the interaction parameters depend on all the species present. Number of Nodes In the Number of Nodes box, choose an appropriate number of nodes for your chosen discretization method. Defining Energy Balance for the Wall This is applicable only if you selected a rigorous model for the heat transfer to the environment. Based on Axial Dispersion This option assumes that the analogy between heat transfer and mass transfer is valid.
Quantitative prediction of behavior requires the simultaneous solution of the mass balance within the particle, as well as for the bulk flow in the bed. It is either constant or estimated from a correlation.
The gas temperature g T and the solid temperature s T are held constant and equal. Solid phase energy balance. While fluid film transfer and pore diffusion are treated as sequential steps, pore diffusion and surface diffusion generally occur in parallel. The type of flow determines whether this term is omitted or included in the material balance.
The gas velocity and pressure are constant along the bed, whilst the gas density is essentially constant along the bed. Quadratic The mass transfer driving force is expressed as a quadratic function of the liquid phase concentration fluid film or solid phase loading solid film. You should base your choice on your knowledge of the actual operating conditions in the plant. Karman-Kozeny Equation Choose this option to use the Karman-Kozeny equation to relate velocity to pressure drop. Both mass density and velocity vary according to the overall mass balance.
Capability to account gas phase nonideality by considering the gas fugacity that may be evaluated by either Aspen Properties or User Procedure. In either case, mean gas phase molecular diffusivities are required for the calculation of film mass transfer coefficients. Under practical conditions in gas separation, pore diffusion limits the overall mass transfer rate between the bulk flow and the internal surface of a particle. User Submodel The name of the submodel is gUserKinetic.
Changes in molar volume between distinct, sequentially fed fluids are allowed. Product release announcements.
Dispersion from wall effects due to non-uniform packing at the wall. You need to supply a constant value for the dispersion coefficient, z E. From molecular diffusion effects. Click Specify to open the specify form for the layer model. The gas phase is ideal or non-ideal, the non-ideal behavior needing a compressibility factor.
The following equation Bird et al. The basic requirements for thermodynamic equilibrium between two phases are that the pressure, temperature and chemical potential of each component are equal in both phases.
Overall and component material balances apply for the liquid phase. Fixed The mean molecular diffusion coefficients are fixed for each component. To define a dynamic simulation flowsheet, uncheck Cyclic Steady-State mode check box and enter the value of Maximum cycle for dynamic simulation. Summary of Factors that affect the Mass Balance Equations This section lists the factors that affect the mass balance in the solid and gas phases. The first commercial operation was in the s, in hydrocarbon processing.
Lumped Resistance Separate mass transfer resistances are lumped as a single overall factor, or one resistance dominates all others. See Form of Lumped Resistance, later.
For details of the Karman-Kozeny model see Bird et al. Plug flow, or plug flow with axial dispersion. It is dimensionless so is more convenient than the dispersion coefficient for this purpose.
The heat of reaction must also be defined as a function of temperature and mole fraction. Constant Density With the Constant Density option, the mass density is constant along the bed. You must specify the value of the wall density w and the specific heat capacity of the wall pw C in the Specify table for the layer. The dispersion coefficient varies with axial position according to the user- supplied submodel iUserDispersion. Qualitatively, a higher pore diffusion rate results in a sharper and steeper concentration wave front, giving a better separation.
Gas wall heat transfer Peclet number
Each pure component isotherm has the same expression as its pure component version. For two dimensional vertical bed models, the heat transfer to the column wall is one of the thermal boundary conditions for the radial direction. Within the pores of the solid. Constant In the Specify table for the layer, set the heat transfer coefficient w H to be a fixed variable.
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